HARBINDONGSHENGMETALCO.,LTD
Material Safety Data Sheet
1.Product Identification:Product name: Mn85%AL15 % Tablet
Manufactory/ Supplier: HARBIN DONGSHENG METAL CO., LTD.( CangZhou Plant2
Tel: +86-451-8450 4713 Fax:+86-451-8450 0228
Informing department: Safety, Health and Environment(S.H.E.)Appearance and odour: Grey to sliver solid, odorless2.CompositionManganese 85%Aluminium 15%CAS# 7439-96-5
3.Hazards identificationConsider the recommended regulations and safety advice(see no.15) there no particular hazards for man andenvironment4.First aid proceduresIn case of dust exposure
INHALATION: in case of discomfort, remove to a ventilated area. If discomfort persists, consult a physicianSKIN CONTACT: in case of burns with hot metal, rinse with plenty of cold water. If burn is severe, consulta physician
EYE CONTACT: Flush eyes thoroughly with water, taking care to rinse under eyelids. if irritation persists,continue flushing for 15mintues,rinsing from time to time under eyelids. If discomfort continues, consult aphysician.
INGESTION: Not applicable5.FIRE-FIGHTING MEASURESEXTINGUISHING MEDIA
Not a fire hazard unless in particle form. Suspensions of manganese dust in air may pose a severe explosionhazard. A potential for explosion exist for a mixture of fine and coarse particles if at least 15% to 20% of thematerial is finer than 44microns(325mesh).buffing and polishing generate finer material than grinding,sawing and cutting. Do not use water or halogenated extinguishing media.HAZARDOUS COMBUSTION PRODUCTS: Not applicable6.Accidental release measureAvoid inhalation of and skin contact with any dust.
Wear suitable respiratory protective equipment and gloves if exposure is considered to be like.
7.Handing and storageHANDING PRECAUTIONS: Because of the risk of explosion, manganese ingot and scrap should bethoroughly dried prior to remelting. Use standard techniques to check metal temperature before handling.hotmanganese does not present any warning color change. Exercise great caution, ,since the metal may be hot.For more information on the handing and storage of manganese, consult the following documents published___________________________________________________________________________________________
Headoffice:Floor10,No.28ChangjiangRoad,NanGangDistrict,HarbinChina
Plant:11ABeihaiRoad,DevelopmentZone,Cangzhou,ChinaTel:+86-451-84500238Cell:+86-13654680860Fax:+86-451-84500228Email:mike@sinodongsheng.net
HARBINDONGSHENGMETALCO.,LTD
by ALUMINIUM ASSOCIATION,
-Guidelines for handling molten manganese
-recommendation for storage and handling of manganese powders and paste
-guidelines for handling manganese fines generated during various manganese fabricating operationsSTORAGE CONDITIONS: Not applicable.
8.Exposure limits/ Personal protective equipmentExposure Limits
OSHA(PEL) -------------------- TWA CELIINGManganese( totald ust) 10mg/m3 none -respirabled ust 4mg/m3 noneAluminium( total dust) 9mg/m3 none -respirabled ust 1mg/m3 none
9.Physical and chemical propertiesPH: Nota pplicable FLASHPOINT:N ota pplicable
Boiling point: Not applicable Autoignition temperature: Not applicableMelting point: 740°C
10. Stability and reactivityStable(yes/no): Yes
Conditions and material to avoid: Molten manganese may explode on contact with water. In the form of particle,may explode when mixed with halogenated acids, halogenated solvents, bromates or ammonium nitrate.Manganese particles on contact with lead, or manganese oxides can react vigorously with release of heat if thereis a source of ignition or intense heat.
HAZARODOUS DECOMPOSITION PRODUCTS: in the form of particles, Iron reacts with water, strong basicsolutions, strong acidic solutions, halogenated acid(eg: hydrofluoric acid)producing flammable hydrogen gas.11. Toxicological informationRoutes of exposure:INHALATION: Yes INGESTION: No
EYE CONTACT: No SKIN CONTACT: No SKIN ABSORPTION: NoACUTE EFFECTS:
INHALATION: Solid t manganese does not present an inhalation hazardSKIN CONTACT: Skin contact with hot metal can cause burns
EYE CONTACT: Manganese dust can irritate the eyes(mechanical abrasion)INGESTION: Not applicable
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE TO THE PRODUCT: Not applicable
12.Ecological informationManganese and its alloys under solid form, such as ingots or manufactured items, do not present any hazard forenvironment because are not biologically available. Iron can be recycled.
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Headoffice:Floor10,No.28ChangjiangRoad,NanGangDistrict,HarbinChina
Plant:11ABeihaiRoad,DevelopmentZone,Cangzhou,ChinaTel:+86-451-84500238Cell:+86-13654680860Fax:+86-451-84500228Email:mike@sinodongsheng.net
HARBINDONGSHENGMETALCO.,LTD
General notes: water hazard class (self classified)S 29: Do not empty into drains. S=safety note
13.DisposalRecycle. Manganese in the form of particle may be reactive. Its hazardous characteristics, including fire andexplosion, should be determined prior to disposal. Dispose of waste in accordance with federal, state, or localregulations.
14.Transportation informationTDGR: not regulated CFR 49: Not regulated IMO: Not regulated ICAO: not regulated15 Regulatory informationWARNING SYMBOL: NoneWARNING WORD: NoneRISK PHRASES: NoneSAFETY PHRASES: None
16.Further informationAlthough the information in this SDS was obtained from sources which we believe to be reliable, it can not beguaranteed. In addition, this information may be used in a manner beyond our knowledge or control. Theinformation is therefore provided or advice purpose only, without any representation or warranty express orimplied.
Department issuing MSDS: SHE manager Ms. Qu Min
Constitutor:Q UM IN RatifierLI LU
EditionOPEA-154221-MN Issued DateJan.21,2016
Signature: QU MIN
Feb.03,2016
HARBIN DONGSHENG METAL CO., LTD.
___________________________________________________________________________________________
Headoffice:Floor10,No.28ChangjiangRoad,NanGangDistrict,HarbinChina
Plant:11ABeihaiRoad,DevelopmentZone,Cangzhou,ChinaTel:+86-451-84500238Cell:+86-13654680860Fax:+86-451-84500228Email:mike@sinodongsheng.net
